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Saved the best for last, of course!
With all the stupid fanwank over the others...what about the guy who ran the show and put em all together!?
NICK FURY NEEDS MORE LOVE!
Also Samuel L. Jackson is badass. So badass that I broke a Stylus nib painting this.
Loved him in The Avengers....especially when he did his Samuel L. Jackson voice. Photoshop CS5
30 hours or so (probably spent the most time and care on the details of his face out of them all)
Airbrush + Texture brushes.
Dodge/Burn and Sharpen/Blur for finishing touches!
Wonderful Lens Flares from: [link]
Original ref: [link]